Hierarchical mesoporous ZSM-5 zeolite with increased external surface acid sites and high catalytic performance in o-xylene isomerization
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چکیده
منابع مشابه
A hierarchical Fe/ZSM-5 zeolite with superior catalytic performance for benzene hydroxylation to phenolw
Phenol is an important industrial intermediate for the production of various chemicals such as bisphenol A, phenolic resins, caprolactam, alkylphenols and adipic acid. The cumene hydroperoxide process is the currently used industrial method to produce phenol. Its environmentally stressing aspects have spurred research to replace this process with more benign approaches such as the direct oxidat...
متن کاملA hierarchical Fe/ZSM-5 zeolite with superior catalytic performance for benzene hydroxylation to phenol.
We report the one-step synthesis of a highly active hierarchical Fe/ZSM-5 zeolite catalyst with a strongly improved lifetime in the selective hydroxylation of benzene to phenol with nitrous oxide; compared to the best Fe/ZSM-5 catalyst, the turnover number after 24 h on stream is almost four times higher.
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Development of highly active heterogeneous catalysts is an effective strategy for modern organic synthesis chemistry. In this work, acidic mesoporous zeolite ZSM-5 (HZSM-5-M), acidic-free mesoporous zeolite TS-1 (TS-1-M), and basic ETS-10 zeolite supported metal Cu catalysts were prepared to investigate their catalytic performances in the hydroxysulfurization of styrenes with diaryl disulfides....
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Zeolite fibers have attracted growing interest for a range of new applications because of their structural particularity while maintaining the intrinsic performances of the building blocks of zeolites. The fabrication of uniform zeolite fibers with tunable hierarchical porosity and further exploration of their catalytic potential are of great importance. Here, we present a versatile and facile ...
متن کاملIsolation and immobilization of alkaline protease on mesoporous silica and mesoporous ZSM-5 zeolite materials for improved catalytic properties
Alkaline protease from brinjal leaf (Solanum melongena) having milk clotting activity has been purified to 9.44 fold to a final specific activity of 45.71 U/mg. SDS-PAGE of the final preparation revealed a single protein band of approx 14 kDa. Purified enzyme was characterized and was successfully immobilized into the amorphous mesoporous silica (SBA-15) and crystalline mesoporous zeolite (Nano...
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ژورنال
عنوان ژورنال: Chinese Journal of Catalysis
سال: 2013
ISSN: 1872-2067
DOI: 10.1016/s1872-2067(12)60602-0